Liquids that climb
Dip a thin glass tube into water and the water climbs inside it, above the level of the surrounding liquid. Dip the same tube into mercury and the level inside drops instead. Both effects come from surface tension and from how well the liquid wets the tube. The English physician James Jurin described the rule in 1718.
Jurin’s law
h = 2γ cos θ ÷ (ρ g r)
- γ: surface tension of the liquid, in N/m
- θ: contact angle between the liquid and the tube wall
- ρ: density of the liquid
- g: gravity, 9.81 m/s²
- r: inner radius of the tube
A contact angle below 90° means the liquid wets the wall and rises; above 90°, it does not wet the wall and is pushed down. The height is inversely proportional to the radius, so the product h × r is constant for a given liquid and surface.
Example
Clean water at 20 °C, with a surface tension of 72.8 mN/m and a contact angle of 0°, in a glass tube with a 0.5 mm radius:
- h = 2 × 0.0728 × 1 ÷ (998 × 9.81 × 0.0005) = 29.75 mm
- In a tube ten times narrower, 0.05 mm, it would rise about 30 cm
Typical properties
| Liquid | γ (mN/m) | ρ (kg/m³) | θ on glass |
|---|---|---|---|
| Water, 20 °C | 72.8 | 998 | about 0° |
| Ethanol | 22.3 | 789 | about 0° |
| Glycerol | 63.4 | 1,261 | about 0° |
| Mercury | 485 | 13,534 | about 140° |
Surface tension falls as temperature rises, and soap or other surfactants lower it sharply, so soapy water rises much less.
The capillary length
The capillary length, √(γ ÷ ρg), is about 2.7 mm for water. Below this scale, surface tension dominates gravity: drops stay round, insects walk on water and liquids climb in narrow gaps. Above it, gravity wins and puddles spread flat.
Capillarity in everyday life
- Rising damp: water climbs through the fine pores of brick and stone walls, which is why old houses without a damp-proof course show damp at the base of their walls.
- Soils: water rises from the water table into fine soils, more in clay than in sand.
- Wicks, paper towels and sponges draw liquids through narrow channels.
- Plants: capillarity helps, but the cohesion of water pulled by evaporation from the leaves does most of the work of raising sap.